Oligomer-containing Aqueous Quench Media Based on Polyethylene Glycol Esters of Oleic Acid

Logvynenko Petro; Moskalenko Anatolii; Karsim Larisa; Glieva Galyna; Riabov Sergii

doi:doi:10.11648/j.ijfmts.20220801.11

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Oligomer-containing Aqueous Quench Media Based on Polyethylene Glycol Esters of Oleic Acid

Logvynenko Petro, Moskalenko Anatolii, Karsim Larisa, Glieva Galyna, Riabov Sergii

Published in International Journal of Fluid Mechanics & Thermal Sciences (Volume 8, Issue 1)

Received: 24 February 2022 Accepted: 18 March 2022 Published: 29 March 2022

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Abstract

The results of studies of the cooling capacity, rheological and surface-active properties of aqueous solutions of oligomers: mono- and dipolyethylene glycol esters of oleic acid are presented. The availability of these oligomeric surfactants and the complex of their physicochemical properties make it possible to obtain, by varying the concentration of components, the compositions of hardening media (QM) with the required indicators. The process of cooling in oligomeric solutions depends on the concentration and stereochemistry of surfactant molecules. An increase in the content of oligomers is accompanied by a decrease in the rate and a shift in the maxima of the cooling rate curves towards low temperatures. As a result of comprehensive studies, a substantiated version of the heat transfer mechanism during cooling of a metal sample in aqueous micellar solutions of oligomeric surfactants was proposed. The stereochemistry of surfactant molecules, the shape of micelles, their strength, and ability to rearrange determine the complex mechanism of adsorption interaction with the metal surface, thus affecting the stages of shock boiling, vapor film, and nucleate boiling, and, ultimately, the intensity of heat transfer and the magnitude of the heat flux.

Published in	International Journal of Fluid Mechanics & Thermal Sciences (Volume 8, Issue 1)
DOI	10.11648/j.ijfmts.20220801.11
Page(s)	1-9
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Quenching Medium, Surfactants, Polyethylene Glycol Oleates, Micellar Solutions, Heat Flux, Heat Transfer Coefficient

References

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APA Style

Logvynenko Petro, Moskalenko Anatolii, Karsim Larisa, Glieva Galyna, Riabov Sergii. (2022). Oligomer-containing Aqueous Quench Media Based on Polyethylene Glycol Esters of Oleic Acid. International Journal of Fluid Mechanics & Thermal Sciences, 8(1), 1-9. https://doi.org/10.11648/j.ijfmts.20220801.11

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ACS Style

Logvynenko Petro; Moskalenko Anatolii; Karsim Larisa; Glieva Galyna; Riabov Sergii. Oligomer-containing Aqueous Quench Media Based on Polyethylene Glycol Esters of Oleic Acid. Int. J. Fluid Mech. Therm. Sci. 2022, 8(1), 1-9. doi: 10.11648/j.ijfmts.20220801.11

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AMA Style

Logvynenko Petro, Moskalenko Anatolii, Karsim Larisa, Glieva Galyna, Riabov Sergii. Oligomer-containing Aqueous Quench Media Based on Polyethylene Glycol Esters of Oleic Acid. Int J Fluid Mech Therm Sci. 2022;8(1):1-9. doi: 10.11648/j.ijfmts.20220801.11

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@article{10.11648/j.ijfmts.20220801.11,
  author = {Logvynenko Petro and Moskalenko Anatolii and Karsim Larisa and Glieva Galyna and Riabov Sergii},
  title = {Oligomer-containing Aqueous Quench Media Based on Polyethylene Glycol Esters of Oleic Acid},
  journal = {International Journal of Fluid Mechanics & Thermal Sciences},
  volume = {8},
  number = {1},
  pages = {1-9},
  doi = {10.11648/j.ijfmts.20220801.11},
  url = {https://doi.org/10.11648/j.ijfmts.20220801.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijfmts.20220801.11},
  abstract = {The results of studies of the cooling capacity, rheological and surface-active properties of aqueous solutions of oligomers: mono- and dipolyethylene glycol esters of oleic acid are presented. The availability of these oligomeric surfactants and the complex of their physicochemical properties make it possible to obtain, by varying the concentration of components, the compositions of hardening media (QM) with the required indicators. The process of cooling in oligomeric solutions depends on the concentration and stereochemistry of surfactant molecules. An increase in the content of oligomers is accompanied by a decrease in the rate and a shift in the maxima of the cooling rate curves towards low temperatures. As a result of comprehensive studies, a substantiated version of the heat transfer mechanism during cooling of a metal sample in aqueous micellar solutions of oligomeric surfactants was proposed. The stereochemistry of surfactant molecules, the shape of micelles, their strength, and ability to rearrange determine the complex mechanism of adsorption interaction with the metal surface, thus affecting the stages of shock boiling, vapor film, and nucleate boiling, and, ultimately, the intensity of heat transfer and the magnitude of the heat flux.},
 year = {2022}
}

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TY  - JOUR
T1  - Oligomer-containing Aqueous Quench Media Based on Polyethylene Glycol Esters of Oleic Acid
AU  - Logvynenko Petro
AU  - Moskalenko Anatolii
AU  - Karsim Larisa
AU  - Glieva Galyna
AU  - Riabov Sergii
Y1  - 2022/03/29
PY  - 2022
N1  - https://doi.org/10.11648/j.ijfmts.20220801.11
DO  - 10.11648/j.ijfmts.20220801.11
T2  - International Journal of Fluid Mechanics & Thermal Sciences
JF  - International Journal of Fluid Mechanics & Thermal Sciences
JO  - International Journal of Fluid Mechanics & Thermal Sciences
SP  - 1
EP  - 9
PB  - Science Publishing Group
SN  - 2469-8113
UR  - https://doi.org/10.11648/j.ijfmts.20220801.11
AB  - The results of studies of the cooling capacity, rheological and surface-active properties of aqueous solutions of oligomers: mono- and dipolyethylene glycol esters of oleic acid are presented. The availability of these oligomeric surfactants and the complex of their physicochemical properties make it possible to obtain, by varying the concentration of components, the compositions of hardening media (QM) with the required indicators. The process of cooling in oligomeric solutions depends on the concentration and stereochemistry of surfactant molecules. An increase in the content of oligomers is accompanied by a decrease in the rate and a shift in the maxima of the cooling rate curves towards low temperatures. As a result of comprehensive studies, a substantiated version of the heat transfer mechanism during cooling of a metal sample in aqueous micellar solutions of oligomeric surfactants was proposed. The stereochemistry of surfactant molecules, the shape of micelles, their strength, and ability to rearrange determine the complex mechanism of adsorption interaction with the metal surface, thus affecting the stages of shock boiling, vapor film, and nucleate boiling, and, ultimately, the intensity of heat transfer and the magnitude of the heat flux.
VL  - 8
IS  - 1
ER  -

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Author Information

Logvynenko Petro

Institute of Macromolecular Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine
Moskalenko Anatolii

Institute of Engineering Thermophysics of National Academy of Sciences of Ukraine, Kyiv, Ukraine
Karsim Larisa

Institute of Macromolecular Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine
Glieva Galyna

Institute of Macromolecular Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine
Riabov Sergii

Institute of Macromolecular Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine

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Plain Text BibTeX RIS

APA Style

Logvynenko Petro, Moskalenko Anatolii, Karsim Larisa, Glieva Galyna, Riabov Sergii. (2022). Oligomer-containing Aqueous Quench Media Based on Polyethylene Glycol Esters of Oleic Acid. International Journal of Fluid Mechanics & Thermal Sciences, 8(1), 1-9. https://doi.org/10.11648/j.ijfmts.20220801.11

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ACS Style

Logvynenko Petro; Moskalenko Anatolii; Karsim Larisa; Glieva Galyna; Riabov Sergii. Oligomer-containing Aqueous Quench Media Based on Polyethylene Glycol Esters of Oleic Acid. Int. J. Fluid Mech. Therm. Sci. 2022, 8(1), 1-9. doi: 10.11648/j.ijfmts.20220801.11

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AMA Style

Logvynenko Petro, Moskalenko Anatolii, Karsim Larisa, Glieva Galyna, Riabov Sergii. Oligomer-containing Aqueous Quench Media Based on Polyethylene Glycol Esters of Oleic Acid. Int J Fluid Mech Therm Sci. 2022;8(1):1-9. doi: 10.11648/j.ijfmts.20220801.11

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@article{10.11648/j.ijfmts.20220801.11,
  author = {Logvynenko Petro and Moskalenko Anatolii and Karsim Larisa and Glieva Galyna and Riabov Sergii},
  title = {Oligomer-containing Aqueous Quench Media Based on Polyethylene Glycol Esters of Oleic Acid},
  journal = {International Journal of Fluid Mechanics & Thermal Sciences},
  volume = {8},
  number = {1},
  pages = {1-9},
  doi = {10.11648/j.ijfmts.20220801.11},
  url = {https://doi.org/10.11648/j.ijfmts.20220801.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijfmts.20220801.11},
  abstract = {The results of studies of the cooling capacity, rheological and surface-active properties of aqueous solutions of oligomers: mono- and dipolyethylene glycol esters of oleic acid are presented. The availability of these oligomeric surfactants and the complex of their physicochemical properties make it possible to obtain, by varying the concentration of components, the compositions of hardening media (QM) with the required indicators. The process of cooling in oligomeric solutions depends on the concentration and stereochemistry of surfactant molecules. An increase in the content of oligomers is accompanied by a decrease in the rate and a shift in the maxima of the cooling rate curves towards low temperatures. As a result of comprehensive studies, a substantiated version of the heat transfer mechanism during cooling of a metal sample in aqueous micellar solutions of oligomeric surfactants was proposed. The stereochemistry of surfactant molecules, the shape of micelles, their strength, and ability to rearrange determine the complex mechanism of adsorption interaction with the metal surface, thus affecting the stages of shock boiling, vapor film, and nucleate boiling, and, ultimately, the intensity of heat transfer and the magnitude of the heat flux.},
 year = {2022}
}

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TY  - JOUR
T1  - Oligomer-containing Aqueous Quench Media Based on Polyethylene Glycol Esters of Oleic Acid
AU  - Logvynenko Petro
AU  - Moskalenko Anatolii
AU  - Karsim Larisa
AU  - Glieva Galyna
AU  - Riabov Sergii
Y1  - 2022/03/29
PY  - 2022
N1  - https://doi.org/10.11648/j.ijfmts.20220801.11
DO  - 10.11648/j.ijfmts.20220801.11
T2  - International Journal of Fluid Mechanics & Thermal Sciences
JF  - International Journal of Fluid Mechanics & Thermal Sciences
JO  - International Journal of Fluid Mechanics & Thermal Sciences
SP  - 1
EP  - 9
PB  - Science Publishing Group
SN  - 2469-8113
UR  - https://doi.org/10.11648/j.ijfmts.20220801.11
AB  - The results of studies of the cooling capacity, rheological and surface-active properties of aqueous solutions of oligomers: mono- and dipolyethylene glycol esters of oleic acid are presented. The availability of these oligomeric surfactants and the complex of their physicochemical properties make it possible to obtain, by varying the concentration of components, the compositions of hardening media (QM) with the required indicators. The process of cooling in oligomeric solutions depends on the concentration and stereochemistry of surfactant molecules. An increase in the content of oligomers is accompanied by a decrease in the rate and a shift in the maxima of the cooling rate curves towards low temperatures. As a result of comprehensive studies, a substantiated version of the heat transfer mechanism during cooling of a metal sample in aqueous micellar solutions of oligomeric surfactants was proposed. The stereochemistry of surfactant molecules, the shape of micelles, their strength, and ability to rearrange determine the complex mechanism of adsorption interaction with the metal surface, thus affecting the stages of shock boiling, vapor film, and nucleate boiling, and, ultimately, the intensity of heat transfer and the magnitude of the heat flux.
VL  - 8
IS  - 1
ER  -

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